LimsPulse
Environmental monitoring

Flame Photometer

Measures sodium, potassium and a few other alkali and alkaline earth metals by spraying a solution into a flame and measuring the light the excited atoms emit at their characteristic wavelengths.

  • Environmental and water testing
  • Agriculture and soil testing
  • Fertiliser manufacture
  • Food and beverage
  • Cement and glass (alkali content)
Photo of a Flame Photometer
Photo: A.KRÜSS Optronic GmbH, CC BY-SA 3.0 de (cropped), via Wikimedia Commons
TROUBLESHOOTING

Common problems, causes and fixes

Reading drifts during a run
Likely causes
  • • Unstable fuel or air pressure
  • • Burner not warmed up
  • • Partly blocked nebuliser
What to do
  • • Check regulators and gas supply
  • • Aspirate water for longer before calibration
  • • Clean the nebuliser and capillary
Low or no signal
Likely causes
  • • Blocked capillary
  • • Wrong filter selected
  • • Flame not lit properly or too lean
What to do
  • • Clear the capillary with a fine wire or by back-flushing
  • • Select the correct filter
  • • Re-light and adjust the flame
Noisy readings
Likely causes
  • • Air bubbles in the sample line
  • • Dirty burner head
  • • Draughts around the flame
What to do
  • • Let samples settle; avoid aspirating from the surface
  • • Clean the burner slot
  • • Shield the instrument from draughts and fume hood airflow
Calibration curve bends at high standards
Likely causes
  • • Self-absorption and ionisation effects
  • • Concentration above linear range
What to do
  • • Narrow the working range
  • • Dilute samples into range
  • • Add an ionisation buffer if the method allows
Results biased high for potassium in sodium-rich water
Likely causes
  • • Spectral or ionisation interference from sodium
What to do
  • • Add matching sodium to the potassium standards
  • • Use an ionisation buffer or measure by AAS / ICP-OES
In LimsPulse · Calibration Management

Keep every Flame photometer in control: usage logs, calibration and maintenance schedules, and automatic blocking of overdue instruments.

See how